Influence of phenol on polymer adsorption at solid-liquid interfaces

Curt Thiesnext term
Materials Research Laboratories, Central Research Division, The National Cash Register Co., Dayton, Ohio 45409, USA
Received 31 January 1968.  Available online 6 July 2004.


The influence of phenol on adsorption of poly(vinyl acetate) (PVAc) and a poly-(ethylene-vinyl acetate) (EVA) copolymer (28.8% vinyl acetate) on finely divided silica has been studied (24░C). Although phenol adsorbs on silica from trichloroethylene (C2HCl3) and cyclohexane (C6H12) in the absence of polymer, concentrations less-than over equal to0.12 M cause only slight reductions in EVA and PVAc adsorbance. On a molar basis, phenol has less effect on polymer adsorbance than had been observed previously for methanol and cycl˛hexanol. Based on changes in the carbonyl ester bands of PVAc and EVA caused by phenol, it interacts more extensively with both polymers in solution than any additive examined to date. Thus, polymer-additive interactions in solution detected spectroscopically are not necessarily directly related to the effect that the additive has on polymer adsorption. This may be related to the fact that phenol adsorbs simultaneously with EVA from C6H12 in such a manner that a silica surface nearly saturated with adsorbed phenol accommodates substantial quantities of EVA.

Journal of Colloid and Interface Science
Volume 27, Issue 4, August 1968, Pages 734-742
Papers Presented at the 42nd National Colloid Symposium